Product ID:GASOLINE 87N
MSDS Date:07/10/1989
FSC:9130
NIIN:01-208-4172
MSDS Number: BRGML

SUN REFINING AND MARKETING COMPANY

1801 MARKET ST.TEN PENN CENTER; 18 FLOOR
PHILADELPHIA, PA 19103
US

Emergency Phone: 215-977-6182 800-964-8861-AFTER HRS

Info Phone: 215-977-6182

Preparer: JOANNE HOUCK

Cage: 8X531

SUN REFINING AND MARKETING COMPANY

PHILADELPHIA, PA 19103-1699 US

Telephone: 215-977-6133

Cage: 8X531

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: .1-4.9%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-30%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0-9%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TERT-BUTYL ALCOHOL (SARA III)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 0-10%

OSHA PEL 100 PPM

ACGIH TLV: 100PPM 9394

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: 0-1%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

NAPHTHALENE (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

OSHA PEL 10 PPM/15 STEL

ACGIH TLV: 10 PPM/15 STEL; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

LD50 LC50 Mixture:ACGIH TLV FOR GASOLINE IS 300PPM
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL:IRRITATES
EYES,NOSE,THROAT;CAUSES CNS EFFECTS,RESPIRATORY
DIFFICULTIES.SKIN:CAUSES DRYING AND IRRITATION.EYES:CAUSES
TEMPORARY PAIN.INGEST:CAN CAUSE LUNG DAMAGE IF VOMITED AFTER
SWALLOWING.CHRON IC:BENZENE IS A CARCINOGEN WHICH AFFECTS THE BLOOD
FORMING ORGANS.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:INHAL:DIZZINESS,LOSS OF BALANCE AND
COORDINATION,UNCONSCIOUSNESS,COMA,RESPIRATORY FAILURE
...COMA,DEATH.
Medical Cond Aggravated by Exposure:HMIS SUGGETS THAT PERSONS WITH
DERMATITIS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHAL:MOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION
IF NEEDED.CALL PHYSICIAN.SKIN:REMOVE CONTAMINATED CLOTHING.WASH
WITH SOAP AND WATER.CALL PHYSICIAN IF IRRITATION
PERSISTS.EYES:QUICKLY FLU SH WITH WATER.CALL PHYSICIAN.INGEST:DO
NOT INDUCE VOMITING!GIVE LIQUIDS;RINSE MOUTH;GET PROMPT QUALIFIED
MEDICAL ATTENTION.IF VOMITING OCCURS,LAY VICTIM ON LEFT SIDE,HEAD
DOWN.

Flash Point:-40F,-40C
Autoignition Temp:Autoignition Temp Text:750F
Lower Limits:1.5
Upper Limits:7.6
Extinguishing Media:WATER FOG,MECHANICAL FOAM,DRY CHEMICAL
POWDER,CARBON DIOXIDE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS.COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE LIQUID(FP<20F).

Spill Release Procedures:PREVENT IGNITION;STOP LEAK;VENTILATE
AREA;CONTAIN SPILL.USE WATER SPRAY TO DISPURSE VAPORS;KEEP UPWIND
OF LEAK.US RESPIRATORY PROTECTION FOR LARGE SPILL.SPILLS INTO
WATERWAYS MUST BE REPORTED.
Neutralizing Agent:NONE

Handling and Storage Precautions:USE NFPA CLASS 1A STORAGE;KEEP AWAY
FROM HEAT,SOURCES OF IGNITION.LIQUID TRANSFERS MUST BE
GROUNDED(FLOWING GAS GENERATES STATIC ELECTRICITY).
Other Precautions:AVOID BREATHING VAPORS AND SKIN CONTACT.KEEP
CONTAINERS CLOSED.EMPTY CONTAINERS ARE AN EXPLOSION HAZARD.

Respiratory Protection:IN THE LACK OF ENVIRONMENTAL CONTROLS,USE A
NIOSH RESPIRATOR.USE A SELF-CONTAINED BREATHIING APPARATUS IN
ENCLOSED SPACES.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION.MECHANICAL VENTILATION
IS RECOMMENDED.
Protective Gloves:IMPERVIOUS TYPE.
Eye Protection:SPLASH PROOF TYPE.
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING TO AVOID SKIN
CONTACT.HAVE EYE WASH AND QUICK DRENCH SHOWER AVAILABLE.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NONE

HCC:F2
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:100F-430F
Vapor Pres:325-525
Spec Gravity:0.74
Evaporation Rate & Reference:RAPID AND VARIES
Solubility in Water:NIL
Appearance and Odor:LIQUID,CLEAR;COLOR NOT REPORTED;GASOLINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STONG OXIDIZERS.
Stability Condition to Avoid:HIGH HEAT AND SOURCES OF IGNTITION.
Hazardous Decomposition Products:CARBON MONOXIDE AND ASPHYXIANTS.

Waste Disposal Methods:RCRA HAZARDOUS
WASTE(TOXIC-BENZENE;IGNITABLE-FP=-40F).DISPOSE OF IN ACCORDANCE
WITH FEDERAL,STATE AND LOCAL REGULATIONS.DO NOT FLUSH DOWN DRAIN OR
SEWER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.